1. Raw Material Preparation
The dry electrode processing begins with the dry blending of three core components:
Active material (e.g., NCM for cathodes, graphite for anodes) determines energy density.
Conductive additives (carbon black, CNTs) compensate for PTFE’s insulation.
PTFE binder (3–5% by weight) replaces solvents, forming a fibrillated network.
Critical requirement: Homogeneous mixing to prevent agglomeration, typically using high-shear planetary mixers.
2. PTFE Fibrillation
During blending or subsequent roller shearing, mechanical force induces PTFE fibrillation—where the binder forms a 3D fibrous mesh. This:
Enhances electrode mechanical strength.
Eliminates the need for solvents (unlike wet slurry processes).
Maintains thermal stability (−200°C to +260°C).
3. Calendering: Dry Powder Compression
The dry mixture is fed into a calender (heated rollers at 80–120°C) under high pressure (10–50 tons) to:
Compress the powder into a freestanding electrode film.
Optimize density (e.g., ~3.4 g/cm³ for anodes).
Challenge: Balancing pressure to avoid cracking the Al/Cu current collectors.
4. Lamination to Current Collectors
The calendered film is thermally bonded to:
Aluminum foil (10–20 µm, cathodes) or copper foil (anodes).
Surface treatments (e.g., laser texturing) improve adhesion.
Key parameter: Precise temperature/pressure control to prevent delamination.
5. Final Assembly & Validation
The dry electrodes are:
Slit to required dimensions.
Integrated into battery cells (e.g., stacked or wound).
Validated for conductivity, porosity, and cycling performance.